Kolen’ko Group
The Nanochemistry research group at the INL focuses on the development of nanomaterials following the strategy CSI: Catalysis, Synthesis and Investigation.
Our mission
Developing creative and interdisciplinary concepts in the area of nanomaterials;
We explore nanochemistry for the development and characterization of advanced catalytic, adsorption, thermoelectric, and electronic materials, addressing key challenges in clean water, low-carbon economy, and clean energy technology. We use a diverse range of methods, combining creative chemistry with cutting-edge nanofabrication;
We aim at understanding fundamental aspects of the synthesized nanoscale objects, specifically finite-size, surface and confinement effects, chemical doping, as well as their formation, nucleation and crystal growth. As experimentalists, we are also interested in testing the limitations of computational prediction.
Research Lines:
- New materials and multi-functional coatings for sustainable solutions (water monitoring and treatment, air purification, smart cities, security, raw materials, manufacturing of added-value goods)
- Advanced nanomaterials for application in energy and catalysis focusing on reducing the dependence on critical raw materials (thermoelectric materials, electrocatalysis, CO2 conversion)
Projects
Publications
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Self–healing core–shell nanofibers for corrosion protective coatings for offshore structures
Progress in Organic Coatings, 2024 -
Large-Scale Colloidal Synthesis of Chalcogenides for Thermoelectric Applications
ACS APPLIED MATERIALS & INTERFACES, 2023One-step synthesis of magnetic covalent organic framework composite for the adsorption of marine toxin okadaic acid
CRYSTENGCOMM, 2023Photocatalytic solid-phase degradation of polyethylene with fluoride-doped titania under low consumption ultraviolet radiation
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2023Retrofitting of carbon-supported bimetallic Ni-based catalysts by phosphorization for hydrogen evolution reaction in acidic media
ELECTROCHIMICA ACTA, 2023 -
A post-synthetic modification strategy for the synthesis of pyrene-fused azaacene covalent organic frameworks
MICROPOROUS AND MESOPOROUS MATERIALS, 2022GO-TiO2 as a Highly Performant Photocatalyst Maximized by Proper Parameters Selection
INTERNATIONAL JOURNAL OF ENVIRONMENTAL RESEARCH AND PUBLIC HEALTH, 2022In situ investigation of the CO2 methanation on carbon/ceria-supported Ni catalysts using modulation-excitation DRIFTS
APPLIED CATALYSIS B-ENVIRONMENTAL, 2022Topotactic BI3-assisted borodization: synthesis and electrocatalysis applications of transition metal borides
JOURNAL OF MATERIALS CHEMISTRY A, 2022Fluoride-Doped TiO2 Photocatalyst with Enhanced Activity for Stable Pollutant Degradation
CATALYSTS, 2022Threefold reactivity of a COF-embedded rhenium catalyst: reductive etherification, oxidative esterification or transfer hydrogenation
CHEMICAL COMMUNICATIONS, 2022Low Lattice Thermal Conductivity in a Wider Temperature Range for Biphasic-Quaternary (Ti,V)CoSb Half-Heusler Alloys
ACS APPLIED MATERIALS & INTERFACES, 2022Deep Eutectic Solvent Synthesis of Perovskite Electrocatalysts for Water Oxidation
ACS APPLIED MATERIALS & INTERFACES, 2022Discovery of Colossal Breathing-Caloric Effect under Low Applied Pressure in the Hybrid Organic-Inorganic MIL-53(Al) Material
CHEMISTRY OF MATERIALS, 2022Implementation of Transition Metal Phosphides as Pt-Free Catalysts for PEM Water Electrolysis
ENERGIES, 2022Polar Layered Intermetallic LaCo2P2 as a Water Oxidation Electrocatalyst
ACS APPLIED MATERIALS & INTERFACES, 2022Structural Properties of Nanometer-Sized Gold Nanoparticles on a Silicon Substrate
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2022Bifunctional atomically dispersed ruthenium electrocatalysts for efficient bipolar membrane water electrolysis_
Inorganic Chemistry Frontiers, 2022Copper Supported on Mesoporous Structured Catalysts for NO Reduction
CATALYSTS, 2022Palladium Impregnation on Electrospun Carbon Fibers for Catalytic Reduction of Bromate in Water
PROCESSES, 2022High Seebeck Coefficient from Screen-Printed Colloidal PbSe Nanocrystals Thin Film
MATERIALS, 2022Synthetic strategy for metallophthalocyanine covalent organic frameworks for electrochemical water oxidation
MATERIALS TODAY CHEMISTRY, 2022Merging solution processing and printing for sustainable fabrication of Cu(In,Ga)Se-2 photovoltaics
CHEMICAL ENGINEERING JOURNAL, 2022Understanding the importance of N−doping for CNT-supported Ni catalysts for CO2 methanation
Carbon, 2022 -
Chapter 8 - Electrocatalysis using nanomaterials
Nanoscale Electrochemistry, Frontiers of Nanoscience, Vol 18, 2021, Pages 343-420, 2021Study on the efficiency of a covalent organic framework as adsorbent for the screening of pharmaceuticals in estuary waters
CHEMOSPHERE, 2021Large-Scale Synthesis of Semiconducting Cu(In,Ga)Se-2 Nanoparticles for Screen Printing Application
NANOMATERIALS, 2021Sustainable catalysts for water electrolysis: Selected strategies for reduction and replacement of platinum-group metals
MATERIALS TODAY SUSTAINABILITY, 2021Photocatalytic-Fenton Process under Simulated Solar Radiation Promoted by a Suitable Catalyst Selection
Catalysts 2021, 11, 885, 2021Acute ecotoxicity assessment of a covalent organic framework
ENVIRONMENTAL SCIENCE-NANO, 2021Boronic-acid-derived covalent organic frameworks: from synthesis to applications
NEW JOURNAL OF CHEMISTRY, 2021Compositional Fluctuations Mediated by Excess Tellurium in Bismuth Antimony Telluride Nanocomposites Yield High Thermoelectric Performance
JOURNAL OF PHYSICAL CHEMISTRY C, 2021Covalent organic framework as adsorbent for ultrasound-assisted dispersive (micro)solid phase extraction of polycyclic synthetic fragrances from seawater followed by fluorescent determination
ANALYTICA CHIMICA ACTA, 2021Eco-friendly and cost-efficient inks for screen-printed fabrication of copper indium gallium diselenide photoabsorber thin films
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2021Large-scale aqueous synthesis of Cu(In,Ga)Se-2 nanoparticles for photocatalytic degradation of ciprofloxacin
DALTON TRANSACTIONS, 2021New Opportunity for Carbon-Supported Ni-based Electrocatalysts: Gas-Phase CO2 Methanation
CHEMCATCHEM, 2021New Opportunity for Carbon-Supported Ni-based Electrocatalysts:Gas-Phase CO2 Methanation
ChemCatChem, 2021PEGylated perylene bisimides: Chromonic building blocks for the aqueous synthesis of nanostructured silica materials
JOURNAL OF MOLECULAR LIQUIDS, 2021Selection of Covalent Organic Framework Pore Functionalities for Differential Adsorption of Microcystin Toxin Analogues
ACS APPLIED MATERIALS & INTERFACES, 2021Silane-based coating charged with TiO2 NPs for dental implant applications
SURFACE & COATINGS TECHNOLOGY, 2021Lithium-copper alloy embedded in 3D porous copper foam with enhanced electrochemical performance toward lithium metal batteries
MATERIALS TODAY ENERGY, 2021Critical Review of Platinum Group Metal-Free Materials for Water Electrolysis: Transition from the Laboratory to the Market Earth-abundant borides and phosphides as catalysts for sustainable hydrogen production
JOHNSON MATTHEY TECHNOLOGY REVIEW, 2021New Functionalized Macroparticles for Environmentally Sustainable Biofilm Control in Water Systems
ANTIBIOTICS-BASEL, 2021 -
Structural properties of PbTe quantum dots revealed by high-energy x-ray diffraction
JOURNAL OF PHYSICS-CONDENSED MATTER, 2020PEGylated perylene bisimides: chromonic building blocks for the aqueous preparation of nanostructured silica materials
JOURNAL OF MOLECULAR LIQUIDS, 2020Covalent Organic Framework Composites: Synthesis and Analytical Applications
MOLECULES, 2020Discovery of Real-Space Topological Ferroelectricity in Metallic Transition Metal Phosphides
ADVANCED MATERIALS, 2020Efficient adsorption of endocrine-disrupting pesticides from water with a reusable magnetic covalent organic framework
MICROPOROUS AND MESOPOROUS MATERIALS, 2020Selectivity boost in partial hydrogenation of acetylene via atomic dispersion of platinum over ceria
CATALYSIS SCIENCE & TECHNOLOGY, 2020Structure of Manganese Oxide Nanoparticles Extracted via Pair Distribution Functions
CONDENSED MATTER, 2020Extraction of Ibuprofen from Natural Waters Using a Covalent Organic Framework
MOLECULES, 20201D materials from ionic self-assembly in mixtures containing chromonic liquid crystal mesogens
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020Chapter 2. New techniques in environment monitoring.
Climate Change and Marine and Freshwater Toxins. De Gruyter, 2020Coagulating and flocculating ferrihydrite: application of zinc acetate salt
ENVIRONMENTAL SCIENCE-WATER RESEARCH & TECHNOLOGY, 2020Crystallographic facet selective HER catalysis: exemplified in FeP and NiP2 single crystals
CHEMICAL SCIENCE, 2020Defect Engineering for Enhancement of Thermoelectric Performance of (Zr, Hf)NiSn-Based n-type Half-Heusler Alloys
JOURNAL OF PHYSICAL CHEMISTRY C, 2020Enhanced oxygen evolution catalysis by aluminium-doped cobalt phosphide through in situ surface area increase
CATALYSIS SCIENCE & TECHNOLOGY, 2020Facile bulk synthesis of high performance beta-Zn4Sb3 for thermoelectric applications
MATERIALS LETTERS, 2020FeP Nanocatalyst with Preferential [010] Orientation Boosts the Hydrogen Evolution Reaction in Polymer-Electrolyte Membrane Electrolyzer
ENERGY & FUELS, 2020Over 6% Efficient Cu(ln,Ga)Se-2 Solar Cell Screen-Printed from Oxides on Fluorine-Doped Tin Oxide
ACS APPLIED ENERGY MATERIALS, 2020Scalable colloidal synthesis of Bi2Te2.7Se0.3 plate-like particles give access to a high-performing n-type thermoelectric material for low temperature application
NANOSCALE ADVANCES, 2020Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale
CATALYSIS SCIENCE & TECHNOLOGY, 2020Synergistic Computational-Experimental Discovery of Highly Selective PtCu Nanocluster Catalysts for Acetylene Semihydrogenation
ACS CATALYSIS, 2020The role of surface properties in CO2 methanation over carbon-supported Ni catalysts and their promotion by Fe
CATALYSIS SCIENCE & TECHNOLOGY, 2020Selective formic acid dehydrogenation at low temperature over a RuO2/COF pre-catalyst synthesized on the gram scale
CATALYSIS SCIENCE & TECHNOLOGY, 2020 -
Sci-fi Miners: a virtual reality journey to the nanocluster scale
PROCEEDINGS OF THE 9TH INTERNATIONAL CONFERENCE ON DIGITAL AND INTERACTIVE ARTS (ARTECH 2019), 2019Enhanced Thermoelectric Performance in Hf-Free p-Type (Ti, Zr)CoSb Half-Heusler Alloys
JOURNAL OF ELECTRONIC MATERIALS, 2019Combined experimental and theoretical study of acetylene semi-hydrogenation over Pd/Al2O3
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019Bi-metallic cobalt-nickel phosphide nanowires for electrocatalysis of the oxygen and hydrogen evolution reactions
CATALYSIS TODAY, 2019Recyclable magnetic covalent organic framework for the extraction of marine biotoxins
NANOSCALE, 2019Zero-dimensional cesium lead halide perovskites: Phase transformations, hybrid structures, and applications
JOURNAL OF SOLID STATE CHEMISTRY, 2019Effectiveness and Safety of a Nontargeted Boost for a CXCR4-Targeted Magnetic Hyperthermia Treatment of Cancer Cells
ACS OMEGA, 2019Electrocatalytic water oxidation over AlFe2B2
CHEMICAL SCIENCE, 2019NiP2: A Story of Two Divergent Polymorphic Multifunctional Materials
CHEMISTRY OF MATERIALS, 2019Superstructural Ordering in Hexagonal CuInSe2 Nanoparticles
CHEMISTRY OF MATERIALS, 2019Tailoring Covalent Organic Frameworks To Capture Water Contaminants
CHEMISTRY-A EUROPEAN JOURNAL, 2019Template-directed self-organization of colloidal PbTe nanocrystals into pillars, conformal coatings, and self-supported membranes
NANOSCALE ADVANCES, 2019 -
Probing of Thermal Transport in 50 nm Thick PbTe Nanocrystal Films by Time-Domain Thermoreflectance
JOURNAL OF PHYSICAL CHEMISTRY C, 2018